Optimal deterministic disturbances rejection control problem for singularly perturbed linear systems is considered. By using the slow-fast decomposition theory of singular perturbation, the existent and unique conditions of the feedforward and feedback composite control (FFCC) laws for both infinite-time and finite-time are proposed, and the design approaches are given. A disturbance observer is introduced to make the FFCC laws realizable physically. Simulation results indicate that the FFCC laws are robust with respect to external disturbances.